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1-烯丙基-6'-硝基吲哚啉螺苯并吡喃染料的合成
Synthesis of 1-Allyl-6'-nitrio-indolino-spiropyran Derivative

1-烯丙基-6'-硝基吲哚啉螺苯并吡喃染料的合成

ISSN:1008-553X
2010年第36卷第2期
科研与开发
孙宾宾1,陈洁2,杨博1 SUN Bin-bin[1],CHEN Jie[2],YANG Bo[1]

以中间体1-烯丙基-2,3,3-三甲基吲哚碘化物与5-硝基水杨醛等为主要试剂,通过两种不同路线合成了题示化合物,并通过1HNMR和IR确证了目标产物的结构。对分步合成路线和以哌啶为催化剂的“一锅法”合成路线进行对比,选择了较优合成路线。

The title compound,1-allyl-6′-nitrio-indolino-spiropyran was synthesized using intermediate 1-allyl-2,3,3-trimethyl-indolenium iodide and 5-nitrosalicylaldehyde as main regents by two different synthesis routes.The structure of title compound was characterized by 1HNMR and IR.The "one-pot"synthesis route which using piperidine as catalysis was compared with the step-by-step synthesis route which using no piperidine.The better synthesis route with the higher yield was given.

关键词: 螺吡喃合成哌啶催化
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ISSN:1008-553X
2010年第36卷第2期
科研与开发

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