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碳纳米管/铅锡复合镀层的腐蚀特征

碳纳米管/铅锡复合镀层的腐蚀特征

ISSN:1005-748X
2010年第31卷第10期
胡正西, 揭晓华, 卢国辉 HU Zheng-xi, JIE Xiao-hua, LU Guo-hui

用复合电沉积方法在黄铜片上制备了碳纳米管/铅锡合金新型减摩复合镀层,对铅锡镀层和碳纳米管/铅锡复合镀层在3.0%(质量分数,下同) HCl、10% NaOH和3.5% NaCl溶液中的极化曲线和电化学阻抗进行了研究.结果表明,碳纳米管/铅锡复合镀层在以上三种介质中的腐蚀电位均有提高,其中,在3.5% NaCl溶液中提高明显,从-0.592 V(SCE)上升到-0.535 V(SCE);复合镀层有更高的电化学阻抗.碳纳米管的添加能提高铅锡镀层的耐蚀性能. Abstract: A carbon nanotube/Pb-Sn alloy new anti-friction composite coating was prepared on a brass sheet by electro-deposition technology.The polarization curves and electrochemical impedance spectroscopy of the Pb-Sn coating and carbon nanotube/Pb-Sn composite coating were tested in 3.0% HCl,10% NaOH and 3.5% NaCl solutions.The results showed that the corrosion potential of the carbon nanotube/Pb-Sn composite coating increased in the three kinds of corrosion media,especially in 3.5% NaCl solution,it increased from -0.592 V(SCE) to -0.535 V(SCE).In addition,the composite coating had higher electrochemical impedance.Carbon nanotubes can improve the corrosion resistance of Pb-Sn plating coatings.

A carbon nanotube/Pb-Sn alloy new anti-friction composite coating was prepared on a brass sheet by electro-deposition technology.The polarization curves and electrochemical impedance spectroscopy of the Pb-Sn coating and carbon nanotube/Pb-Sn composite coating were tested in 3.0% HCl,10% NaOH and 3.5% NaCl solutions.The results showed that the corrosion potential of the carbon nanotube/Pb-Sn composite coating increased in the three kinds of corrosion media,especially in 3.5% NaCl solution,it increased from-...

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ISSN:1005-748X
2010年第31卷第10期

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