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The infrared part of the C2 Phillips system (2.3–0.9 μm)

ISSN:0022-2852
1977年第68卷第3期

Line positions and molecular constants for the 0-0, 1-0, 2-0, 0-1, 2-1, 3-1, 0-2, 1-2, and 4-2 bands of the C2 Phillips system (A 1Πu-X 1Σg+) are reported. Among them, five bands have not been reported previously. Rotational perturbations have been observed in the previously unobserved v = 1 level of the A 1Πu state. This state is perturbed by the c 3Σu+ state which was discovered by Ballik and Ramsay. These observations provide new information regarding the perturbing state. In particular, the minimum of the potential energy for the c 3Σu+ state has been found to be at 9227.4 cm?1 instead of 13 310 cm?1, which was the previous Te value for this electronic state.

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ISSN:0022-2852
1977年第68卷第3期

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