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活性炭负载Fe~(3+),Cu~(2+)微波诱导氧化甲基橙

活性炭负载Fe~(3+),Cu~(2+)微波诱导氧化甲基橙

ISSN:1007-1032
2008年第34卷第5期
王书敏[1],杨成建[2] WANG Shu-min[1],YANG Cheng-jian[2]
  1. 重庆文理学院,化学与环境科学系,重庆,402168
  2. 西安建筑科技大学,环境与市政工程学院,陕西,西安,710055

以活性炭为载体,采用浸渍-焙烧法制备了负载Fe3 ,Cu2 活性炭催化剂,并将其应用于微波诱导催化氧化处理甲基橙废水,优化了处理工艺条件.在相同去除条件下,3种改性前后活性炭催化剂对微波诱导氧化甲基橙的去除效率从大到小依次为负载Fe3 活性炭,负载Cu2 活性炭,未改性活性炭;微波催化氧化去除甲基橙最佳条件为:微波辐射功率480 W,辐射时间6 min,催化剂质量浓度40 g/L,pH为3;在该条件下,以负载Fe3 活性炭为催化剂,甲基橙的去除率可达80%以上;改性活性炭催化剂通过表面吸附-微波诱导氧化协同作用极大地提高了对甲基橙的去除效率.

Activated carbon was modified with Fe3+ and Cu2+ by dipping-calcination method,and a microwave induced oxidation process which was optimized was developed to treat methyl orange water. Under the same conditions,the effect of Fe3+-modified activated carbon was better than that of Cu2+-modified activated carbon,while the effect of Cu2+-modified activated carbon was better than that of common activated carbon. Under optimum conditions of irradiation time 6 min, microwave power 480W,amount of sorbent 40g/L and ...

关键词: 微波甲基橙改性活性炭诱导氧化
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ISSN:1007-1032
2008年第34卷第5期

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